PMMA-I / PMMA (Polymethylmethacrylate/acrylic) Material Data Sheet (impact modified)
PMMA (impact modified) Designation
| Polymethylmethacrylate (Impact Modified, Molding and Extrusion) |
PMMA (impact modified) Tradenames
| Acryl, Acrylite, Altuglas, Cyrolite, Diakon, Optix, Plexiglas, Terez |
PMMA (impact modified) Typical uses
| Light fittings, display signs, domestic baths, packaging, safety spectacles, tool handles, motorcycle windscreens, baby incubators |
PMMA (impact modified) Compositional summary
| (CH2-C(CH3)COOCH3)n | |
| Material family | Plastic (thermoplastic, amorphous) |
| Base material | PMMA (Polymethyl methacrylate / acrylic) |
| Additive | Impact modifier |
| Polymer code | PMMA-I |
PMMA (impact modified) Composition Detail
| Polymer | 85 | – | 95 | % |
| Impact modifier | 5 | – | 15 | % |
PMMA (impact modified) Physical Properties
| Density | 1.11 | – | 1.18 | g/cm3 |
PMMA (impact modified) Mechanical Properties
| Young’s modulus | 1.6 | – | 3.3 | GPa |
| Specific stiffness | 1.4 | – | 2.89 | MN.m/kg |
| Yield strength (elastic limit) | 37.9 | – | 58.4 | MPa |
| Tensile strength | 34.5 | – | 62.1 | MPa |
| Specific strength | 33.1 | – | 51.1 | kN.m/kg |
| Elongation | 4.6 | – | 70 | % strain |
| Compressive modulus | 1.65 | – | 2.54 | GPa |
| Compressive strength | 43.9 | – | 96.5 | MPa |
| Flexural modulus | 1.38 | – | 2.96 | GPa |
| Flexural strength (modulus of rupture) | 48.3 | – | 96.5 | MPa |
| Shear modulus | 0.493 | – | 1.23 | GPa |
| Bulk modulus | 3.5 | – | 3.68 | GPa |
| Poisson’s ratio | 0.389 | – | 0.413 | |
| Shape factor | 5.2 | |||
| Hardness – Vickers | 11 | – | 18 | HV |
| Hardness – Rockwell M | 35 | – | 78 | |
| Hardness – Rockwell R | 82 | – | 90 | |
| Elastic stored energy (springs) | 292 | – | 795 | kJ/m3 |
| Fatigue strength at 10^7 cycles | 13.8 | – | 24.8 | MPa |
PMMA (impact modified) Impact & Fracture Properties
| Fracture toughness | 1.81 | – | 2.18 | MPa.m0.5 |
| Toughness (G) | 1.16 | – | 2.54 | kJ/m2 |
| Impact strength, notched 23 °C | 3.34 | – | 7.25 | kJ/m2 |
| Impact strength, notched -30 °C | 3.18 | – | 3.85 | kJ/m2 |
| Impact strength, unnotched 23 °C | 29.7 | – | 78.8 | kJ/m2 |
| Impact strength, unnotched -30 °C | 40.9 | – | 49.5 | kJ/m2 |
PMMA (impact modified) Thermal Properties
| Glass temperature | 96 | – | 104 | °C |
| Heat deflection temperature 0.45MPa | 92 | – | 99 | °C |
| Heat deflection temperature 1.8MPa | 85 | – | 93 | °C |
| Vicat softening point | 94 | – | 100 | °C |
| Maximum service temperature | 80 | – | 95 | °C |
| Minimum service temperature | -75 | – | -65 | °C |
| Thermal conductivity | 0.167 | – | 0.209 | W/m.°C |
| Specific heat capacity | 1.4e3 | – | 1.52e3 | J/kg.°C |
| Thermal expansion coefficient | 86.4 | – | 144 | µstrain/°C |
| Thermal shock resistance | 116 | – | 290 | °C |
| Thermal distortion resistance | 0.00127 | – | 0.0022 | MW/m |
PMMA (impact modified) Electrical Properties
| Electrical resistivity | 3.3e23 | – | 3e24 | µohm.cm |
| Electrical conductivity | 5.75e-23 | – | 5.22e-22 | %IACS |
| Dielectric constant (relative permittivity) | 2.7 | – | 2.9 | |
| Dissipation factor (dielectric loss tangent) | 0.03 | – | 0.04 | |
| Dielectric strength (dielectric breakdown) | 15 | – | 19.7 | MV/m |
| Comparative tracking index | 600 | V |
PMMA (impact modified) Magnetic Properties
| Magnetic type | Non-magnetic |
PMMA (impact modified) Optical, aesthetic and acoustic properties
| Refractive index | 1.49 | – | 1.5 | |
| Transparency | Transparent | |||
| Acoustic velocity | 1.16e3 | – | 1.73e3 | m/s |
| Mechanical loss coefficient (tan delta) | 0.0116 | – | 0.029 | |
PMMA (impact modified) Absorption & permeability
| Water absorption @ 24 hrs | 0.19 | – | 0.8 | % | |
| Water vapor transmission | 1.62 | – | 1.79 | g.mm/m².day | |
| Permeability (O2) | 4.31 | – | 7.19 | cm³.mm/m².day.atm |
PMMA (impact modified) Processing properties
| Polymer injection molding | Acceptable | |||
| Polymer extrusion | Excellent | |||
| Polymer thermoforming | Acceptable | |||
| Linear mold shrinkage | 0.2 | – | 0.8 | % |
| Melt temperature | 190 | – | 260 | °C |
| Mold temperature | 50 | – | 65 | °C |
| Molding pressure range | 34.4 | – | 138 | MPa |
PMMA (impact modified) Durability
| Water (fresh) | Excellent |
| Water (salt) | Excellent |
| Weak acids | Acceptable |
| Strong acids | Unacceptable |
| Weak alkalis | Excellent |
| Strong alkalis | Excellent |
| Organic solvents | Unacceptable |
| Oxidation at 500C | Unacceptable |
| UV radiation (sunlight) | Good |
| Flammability | Highly flammable |
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